Writing Reaction Mechanisms in Organic Chemistry

  • Format
  • Bog, paperback
  • Engelsk

Beskrivelse

Writing Reaction Mechanisms in Organic Chemistry, Third Edition, is a guide to understanding the movements of atoms and electrons in the reactions of organic molecules. Expanding on the successful book by Miller and Solomon, this new edition further enhances your understanding of reaction mechanisms in organic chemistry and shows that writing mechanisms is a practical method of applying knowledge of previously encountered reactions and reaction conditions to new reactions. The book has been extensively revised with new material including a completely new chapter on oxidation and reduction reactions including stereochemical reactions. It is also now illustrated with hundreds of colorful chemical structures to help you understand reaction processes more easily. The book also features new and extended problem sets and answers to help you understand the general principles and how to apply these to real applications. In addition, there are new information boxes throughout the text to provide useful background to reactions and the people behind the discovery of a reaction. This new edition will be of interest to students and research chemists who want to learn how to organize what may seem an overwhelming quantity of information into a set of simple general principles and guidelines for determining and describing organic reaction mechanisms.

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Detaljer
  • SprogEngelsk
  • Sidetal510
  • Udgivelsesdato12-08-2014
  • ISBN139780124114753
  • Forlag Academic Press Inc
  • FormatPaperback
Størrelse og vægt
  • Vægt1040 g
  • coffee cup img
    10 cm
    book img
    19,1 cm
    23,5 cm

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    Migration Initiation Wolf Decomposition Acid Hydrolysis Oxidation Stability Lewis Hybridization Fragmentation reactions Resonance Termination Hydrogenation Propagation Ionization Ozone Solvents Bond Stereochemistry Inhibitors Reduction Ozonolysis Enthalpy Basicity Electronegativity Homo Atomic orbitals Nitrenes tempo: Hydrogen Transfer Electrophile Balancing equations Ozonide Radical Epoxidation Mechanisms Lumo Acidity Nodes Jones Nucleophile Ring-Opening Condensation Reactions Base Deuterium Collins Pericyclic Reactions Aromaticity Beckmann Ene reaction Products Heterogeneous Rearrangement Dipole Activation Insertion Catalytic Cycle Photochemical Reactions Free-Radical Wacker-Oxidation Chargé Borane Acids and Bases Hydroboration Substitution reaction Orbitals Cycloadditions Homogeneous Activated sulfoxide Allyl cation Antiperiplanar Anti-addition Axis of symmetry Benzilic acid rearrangement AIBN Aromatic substitution Baeyer-Villiger Birch reduction Antarafacial carbenes Carbocation Concerted Complexation cram Chain processes Crabtree catalyst Conservation of orbital symmetry Charged species Electron poor E2 Diborane Energy barrier Favorskii rearrangement Felkin-Anh Electrocyclic transformations Ene reactions Cope rearrangement Conrotatory Frontier molecular orbitals Formal charge Frontier orbital theory Imines Directed hydrogenations Disrotatory processes Diimide Inductive effect Interconversion Electron rich Hydrogen abstraction eliminations Electron deficient Leuche conditions Facial selectivity Nucleophilic Manganese dioxide Markownikov nucleophiles organometallic reagents Overoxidaiton Oxidation number Peracid Geometric constraint Precomplexation Homolytic cleavage Hydrogen shift permanganate Reimer-Tiemann Protonation Sigmatropic reactions Radical coupling Intramolecular Pyridinium dichromate (PDC) oxidation Starting materials Reductive aminations Suprafacial Symmetry-forbidden SN2 reaction Thermal initiation Thermal reactions Tautomers Leaving groups Lithium Aluminum Hydride Swern Symmetry-allowed Lewis Structure Neighboring group Pyridinium chlorochromate (PCC) octet Meerwein-Pondorff-Verley reduction Oppenauer oxidation Moebius-Huckel theory Moffat Perborate Periodinate Photochemical initiation Selection rules for electrocyclic reactions Orbital overlap Oxidation state radical cyclization Sodium borohydride Secondary interactions Syn addition Selection rules SIGMATROPIC REARRANGEMENTS Zwitterionic intermediate Wilkinson catalyst

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