Physical Oceanography of the Frontal Zones in Sub-Arctic Seas

Theoretical Aspects of Chemical Reactivity provides a broad overview of recent theoretical and computational advancements in the field of chemical reactivity. Contributions have been made by a number of leaders in the field covering theoretical developments to applications in molecular systems and clusters. With an increase in the use of reactivity descriptors, and fundamental theoretical aspects becoming more challenging, this volume serves as an interesting overview where traditional concepts are revisited and explored from new viewpoints, and new varieties of reactivity descriptors are proposed. Includes applications in the frontiers of reactivity principles, and introduces dynamic and statistical viewpoints to chemical reactivity and challenging traditional concepts such as aromaticity.This volume represents an effort to bring together communities of land-based hydrogeology and marine hydrogeology. The issues of submarine groundwater discharge and its opposite phenomenon of seawater invasion are discussed in this book from the geophysical, geochemical, biological, and engineering perspectives. This is where land hydrogeology and marine hydrogeology overlap. Submarine groundwater discharge is a rapidly developing research field. The SCOR and LOICZ of the IGBP have recently established a working group for this research. IASPO and IAHS under IUGG also recently formed a new joint committee "Seawater/Groundwater Interactions" to collaborate with oceanographers and hydrologists. The other articles introduce frontier research topics in more typical land and marine environments, such as fluid flow in karst aquifers, the biological aspects of fluids in sedimentary basins and submarine sedimentary formations, respectively, and vigorous fluid flow in subsea formations and their significance in global tectonics. Geochemical characteristics of hydrothermal activities at a number of active continental margins are also reviewed, and multidisciplinary geophysical constraints of the permeability of young igneous oceanic crust are summarized. A variety of driving mechanisms for fluid flow is discussed in land and subsea formations; terrestrial hydraulic gradient, buoyancy driven free convection, tidally induced flow, flow induced by tectonic strain, flow due to sediment compaction.This title presents the systematization and description of accumulated knowledge on oceanic fronts of the Norwegian, Greenland, Barents and Bering Seas. The main fronts of the Norwegian, Greenland and Barents Seas are part of the climatic North Polar Frontal Zone (NPFZ). The work is based on numerous observational data, collected by the authors during special sea experiments directed at the investigation of physical processes and phenomena inside certain parts of the NPFZ and in the northern part of the Bering Sea, on archive data of the USSR Hydrometeocenter and other research institutions, as well as on a wide scientific literature published in Russian and Western editions.The book contains general information on the oceanic fronts of the Subarctic Seas, brief history of their investigation, state of the knowledge, as well as detailed description of the thermohaline structure of all frontal zones in the Norwegian, Greenland, Barents and Bering Seas and of neighboring fronts of Arctic and coastal origin. Special attention is given to the study of the multifrontal character of the NPFZ and of peculiarities of its internal structure at different locations, to the description of diverse oceanic features observed in the NPFZ, as well as to some characteristics of the horizontal and vertical fine structure of hydrophysical fields in the NPFZ. The main features of the northern Bering Sea's summer ecohydrodynamics are investigated with the help of three-dimensional direct and inverse models.