Efficient Methods for Preparing Silicon Compounds

  • Format
  • Bog, paperback
  • Engelsk

Beskrivelse

Efficient Methods for Preparing Silicon Compounds is a unique and valuable handbook for chemists and students involved in advanced studies of preparative chemistry in academia and industry. Organized by the various coordination numbers (from two to six) of the central silicon atom of the reported compounds, this book provides researchers with a handy and immediate reference for any compound or properties needed in the area. Edited by a renowned expert in the field, each chapter explores a different type of compound, thoroughly illustrated with useful schemes and supplemented by additional references. Knowledgeable contributors report on a broad range of compounds on which they have published and which are already used on a broad scale or have the potential to be used in the very near future to develop a new field of research or application in silicon chemistry.

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Detaljer
  • SprogEngelsk
  • Sidetal538
  • Udgivelsesdato07-06-2016
  • ISBN139780128035306
  • Forlag Academic Press Inc
  • FormatPaperback
Størrelse og vægt
  • Vægt1450 g
  • coffee cup img
    10 cm
    book img
    19,1 cm
    23,5 cm

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    Crystallization. Electrochemistry Hydrolysis Metal complexes Alkoxysilanes X-ray crystallography Catalysis Phosphorus Chromatography Silicon Condensation Synthesis Hydrosilylation Silicon compounds Sulfur X-ray diffraction Siloxanes Silane Homogeneous catalysis Transesterification N-Heterocyclic Carbene Hydrogen Transfer Small-molecule Activation Cage compounds Pincer ligands Cross-coupling Carbene Ligands Lewis acid Cross Metathesis NHC Silylenes Dendrimer Silsesquioxanes Silsesquioxane Oligosilanes Heterocycles Amorphous silicon Aromaticity Oxidative Addition POSS Alkene Hydroformylation Silylene Activation Lewis-Base Insertion Complex CVD Carbodiimide Hybrid Racking R/3 Nucleophilic substitution Cycloaddition reactions Borane 1H-NMR 29Si-NMR Polycrystalline silicon Silene NICs Zwitterion Acetonitrile complex Acylation of N-(Silylmethylamines)N-alkylation Ambiphilic character Alkali metal amide Ammoniates Alkoxysilane Allylsilane Amine complexes Benzophenone Arsasilene Bis(silylene)Catalyst Bis(silylene) complex Arylsilanes azide Anhydrous ammonia Birch reduction Bis-silylene Carbene adducts Aryllithium Conjugated dienes cAAC Cyclohexadienes Cylcobutadiene Diazoesters Cubic silica Cobalt compounds Branched polysilane Cyclodisiloxane Cage silsesquioxane Carbosilanes Cationic silicon(IV) complexes Disiletane Chlorotrimethylsilane Disilene Chromium compound Cyclic silanol Cyclic siloxane DDSQ Dichlorosilylene DISILANES Electrophilic activation Conformations Cyclic silane HOMO�LUMO Cryostat Functionalized disilenes Dehydrochlorination Donor�acceptor Hydrido-silyl complexes Hydroxymethylation of a Double-bonded complexes HMPA Ladder silsesquioxane Insertion reactions Inorganic�organic hybrid materials Intramolecular hydrosilylation Metal-silyl complexes N-heterocyclic carbene (NHC)Pentacoordinate derivatives Metal-containing precursors Functionalized siloxanes NMR investigations N-silylmethylimides o-Phenylene Nitrogen-containing groups [n]Staffanes Phosphasilene HOMO�LUMO gap Optimal conditions ω-bis(hydroxy)polysiloxanes Phosphine Hyperbranched Polymers Silanetriols Silicon(II) compounds Silicon tetrafluoride Silylamines Silyl Esters Silyl radical Silaallene Single-crystal X-ray analysis SiOReO3 Spacers SiH bond activation silanol Silicon(IV) compounds Small rings Sodiumoxysilane Lewis-acid catalyzed polymerization Linear siloxane Siliranes Silyliumylidene Silyloxonium Hexamethyldisiloxane SiSi double bond Silamacrocycles Silicochloroform Silicon(II) complexes Silver perrhenate Silyl anion Hydrosilane Transition metal complex Triarylborane Tetra(silyl)methane Silabenzene Well-ventilated hood Small Ring Tosic acid Spirosiloxane N-silylmethyllactams Metallocarbene X-ray structures photolysis reactions N-silylmethylamides N-silylmethylcarbamates and N-silylmethylureas Pt-NHC-Complexes Three- and five-membered rings Ruthenium compounds Polyfunctional reagents Silacyclopropylidene Siletanes Silylation of a-nitrogen carbanion Silyl cation Rhenium heptoxide Rhodium catalysis Tungsten compounds SHOP process Silanols Silylene complexes Quasihomogenous reaction Vinyl lithium analog Soluble aluminosiloxanes Sacrificial anode Silamine Silicon carbene-transfer hypervalent complexes Silylative coupling Silylium Three-center bonds Tin(IV) catalysis Two-phase catalysis Unsymmetrical disilenes X-ray structure

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