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Bog, paperback Group 2 Mediated Dehydrocoupling af David J Liptrot

Group 2 Mediated Dehydrocoupling (Springer Theses)

(Bog, paperback)

166 black & white illustrations, 3 colour illustrations, biography

166 black & white illustrations, 3 colour illustrations, biography

Produktdetaljer:

Sprog:
Engelsk
ISBN-13:
9783319370330
Sideantal:
177
Udgivet:
04-11-2016
Udgave:
Softcover reprint of the original 1st ed. 2016
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Forlagets beskrivelse
166 black & white illustrations, 3 colour illustrations, biography
Bibliotekernes beskrivelse
This book presents an in-depth study into the utility of sigma-bond metathesis in Group 2 mediated reactivity. A comprehensive introduction defines the state of the art in both Group 2 mediated catalysis and dehydrocoupling. Structural investigations giving rise to a range of mixed s-block metal hydrides including a remarkable dodecabimetallic decahydride are then described. Subsequent extensive mechanistic work focussing on both silicon-nitrogen and boron-nitrogen dehydrocoupling gives insights into both congeneric effects down Group 2 and ligand effects centring upon magnesium. These studies show the striking effects of these factors, as well as the electronic nature of the hydridic coupling partner. Finally, the unprecedented introduction of single-electron transfer steps into Group 2 catalytic manifolds is described. The use of the stable radical TEMPO to induce single-electron transfer to substituents bound to Group 2 centres coupled with sigma-bond metathesis allows a novel hydrogen release from silanes.

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